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Sigma-Aldrich

Poly(ethylene glycol) bis(2-bromoisobutyrate)

average Mn 1,000

Synonym(s):

PEG ATRP initiator, PEG BIBB

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About This Item

Linear Formula:
C4H6O2Br(C2H4O)nC4H6OBr
UNSPSC Code:
12162002
NACRES:
NA.23

form

solid

mol wt

PEG Mn 1,000
average Mn 1,000

mp

>250 °C

storage temp.

2-8°C

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General description

Degree of functionality: >= 90%

Application

Poly(ethylene glycol) Macroinitiator useful for the inclusion of a PEG block via controlled radical polymerization.
Poly(ethylene glycol)-containing ATRP initiator for generating a triblock copolymer with a PEG block in the center.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBK3995V

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Articles

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Protocols

Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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