442305
Bis(ethylenediamine)copper(II) hydroxide solution
1.0 M in H2O
Synonym(s):
Copper(II)-ethylenediame complex
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About This Item
Linear Formula:
Cu(H2NCH2CH2NH2)2(OH)2
CAS Number:
Molecular Weight:
217.76
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.23
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form
liquid
reaction suitability
reagent type: catalyst
core: copper
concentration
1.0 M in H2O
density
1.086 g/mL at 25 °C
SMILES string
O[Cu]O.NCCN.NCCN
InChI
1S/2C2H8N2.Cu.2H2O/c2*3-1-2-4;;;/h2*1-4H2;;2*1H2/q;;+2;;/p-2
InChI key
WATCRQGYOIZIHC-UHFFFAOYSA-L
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General description
Bis(ethylenediamine)copper(II) hydroxide solution is a stable complex formed by copper (Cu) ions with ethylenediamine. It is a transition metal solution that can be used as a catalyst for electrochemical reduction process.
Application
Bis(ethylenediamine)copper(II) hydroxide has been used to evaluate cation exchange capacity (CEC) of clays by copper absorption.
Copper(II) ethylenediamine complex may be used to evaluate the cation exchange capacity (CEC) of clay materials. It may also be used to modify polyoxoniobate, which is a class of polyoxometalates (POMs) that finds potential application in photocatalytic H2 production.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Far-infrared and electronic spectra of some bis (ethylenediamine) and related complexes of copper (II) and the relevance of these data to tetragonal distortion and bond strengths.
Lever ABP and Mantovani E
Inorganic Chemistry, 10(4), 817-826 (1971)
CEC of clays: measurement by adsorption of a copper ethylenediamine complex
Bergaya F and Vayer M
Applied Clay Science, 12(3), 275-280 (1997)
Determination of the cation exchange capacity (CEC) of clay minerals using the complexes of copper (II) ion with triethylenetetramine and tetraethylenepentamine.
Lorenz P, et al.
Clays and Clay Minerals, 47, 386-388 (1999)
A copper (ii)-ethylenediamine modified polyoxoniobate with photocatalytic H2 evolution activity under visible light irradiation.
Wang Z, et al.
Dalton Transactions, 41(33), 9882-9884 (2012)
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