298190
Cerium(III) chloride
AnhydroBeads™, −10 mesh, 99.9%
Synonym(s):
Cerium trichloride, Cerous chloride
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About This Item
Empirical Formula (Hill Notation):
CeCl3
CAS Number:
Molecular Weight:
246.48
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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product line
AnhydroBeads™
Quality Level
Assay
99.9%
reaction suitability
reagent type: catalyst
core: cerium
impurities
≤1500.0 ppm Trace Rare Earth Analysis
particle size
−10 mesh
mp
848 °C (lit.)
density
3.97 g/mL at 25 °C (lit.)
SMILES string
Cl[Ce](Cl)Cl
InChI
1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VYLVYHXQOHJDJL-UHFFFAOYSA-K
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Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.
Legal Information
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
accessory
Product No.
Description
Pricing
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 2
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Xiao, Z. Timberlake, J.W.
Tetrahedron, 54, 4211-4211 (1998)
Florian J Wegehaupt et al.
Archives of oral biology, 55(6), 441-446 (2010-04-20)
To investigate the effect of cerium chloride, cerium chloride/fluoride and fluoride application on calcium release during erosion of treated dentine. Forty dentine samples were prepared from human premolars and randomly assigned to four groups (1-4). Samples were treated twice a
Haiquan Zhao et al.
Archives of environmental contamination and toxicology, 62(1), 154-164 (2011-04-20)
Cerium has been demonstrated to damage liver of mice, but very little is known about the molecular mechanisms underlying the mouse liver apoptosis. In order to understand the liver injury induced by intragastric administration of cerium chloride (CeCl3) for 60
Zhe Cheng et al.
Environmental toxicology, 27(12), 707-718 (2011-03-09)
Experimental studies have demonstrated that lanthanides could impair cognitive functions of children and animals, but very little is known about the hippocampal apoptosis and its molecular mechanism. The study investigated the signal pathway of hippocampal apoptosis induced by intragastric administration
Qinghua Meng et al.
The Journal of organic chemistry, 73(10), 3842-3847 (2008-04-24)
In the presence of catalytic amounts of CeCl 3.7H 2O, [RuCl(benzene)(S)-SunPhos]Cl is a highly effective catalyst for the asymmetric hydrogenation of aromatic alpha-ketoesters. A variety of ethyl alpha-hydroxy-alpha-arylacetates have been prepared in up to 98.3% ee with a TON up
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