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200956

Sigma-Aldrich

Hexafluorophosphoric acid solution

~55 wt. % in H2O

Synonym(s):

Hydrogen hexafluorophosphate

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About This Item

Linear Formula:
HPF6
CAS Number:
16940-81-1
Molecular Weight:
145.97
MDL number:
MFCD00011350
UNSPSC Code:
12352301
PubChem Substance ID:
24851984
NACRES:
NA.22

form

liquid

Quality Level

100

concentration

~55 wt. % in H2O

density

1.651 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

F.FP(F)(F)(F)F

InChI

1S/F5P.FH/c1-6(2,3,4)5;/h;1H

InChI key

OQWOLAMXNGPSQY-UHFFFAOYSA-N

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General description

Hexafluorophosphoric acid (HPF6) is a strong acid that is commonly used as a catalyst in organic synthesis. It is also used in the polymerization and preparation of its salts.

Application

Hexafluorophosphoric acid solution is used as a catalyst for the conversion of polyethyleneimine (PEI) microgel into the corresponding polymeric ionic liquids (PIL) forms via protonation and anion exchange reaction. Polymeric ionic liquids are used as metal-free catalysts for hydrogen production via sodium borohydride methanolysis.

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H290,H301,H310,H314,H332

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN3283
MKCM5356
SHBK2376
SHBG9289V
SHBF4445V

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The Use of Hexafluorophosphoric Acid in the Schiemann Reaction
Rutherford KG, et al.
The Journal of Organic Chemistry, 26(12), 5149-5152 (1961)
Product Class 12: Telluropyrylium and Benzotelluropyrylium Salts
Murphy PJ et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations null

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