189138

Tetrabutylphosphonium bromide

98%

• Synonym(s): Tetra-n-butylphosphonium bromide
• Linear Formula: (CH₃CH₂CH₂CH₂)₄P(Br)
• CAS Number: 3115-68-2
• Molecular Weight: 339.33
• Beilstein: 4160474
• EC Number: 221-487-8
• MDL number: MFCD00011853
• UNSPSC Code: 12352001
• PubChem Substance ID: 24851366
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: 98%
• form: solid
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• mp: 100-103 °C (lit.)
• greener alternative category: , Aligned
• SMILES string: [Br-].CCCC[P+](CCCC)(CCCC)CCCC
• InChI: 1S/C16H36P.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
• InChI key: RKHXQBLJXBGEKF-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Tetrabutylphosphonium bromide (TBPB) is a quaternary salt which can be used:

• As a medium to disperse ruthenium catalyst for the synthesis of ethylene glycol from synthesis gas via ruthenium melt catalysis.
• As a catalyst supported on silica or alumina for the halogen exchange reaction to synthesize alkyl bromide from alkyl chloride.
• To synthesize various ionic liquids on mixing with different proportions of 1,3-dimethylurea for capturing NO gas.
• As a hydrogen-bond acceptor along with levulinic acid as a hydrogen-bond donor for the preparation of deep eutectic solvents to separate toluene from toluene/n-hexane mixtures.
• To prepare ionic semiclathrate hydrates.

Safety Information

• Pictograms: GHS05,GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H290 - H302 - H311 - H317 - H318 - H361fd - H411
• Precautionary Statements: P273 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Repr. 2 - Skin Sens. 1B
• Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flash Point(F): 554.0 °F - closed cup
• Flash Point(C): 290 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves