394262

Octadecylmagnesium chloride solution

0.5 M in THF

• 別名: Chlorooctadecylmagnesium, Octadecane, magnesium complex
• 化学式: CH₃(CH₂)₁₇MgCl
• CAS番号: 116980-66-6
• 分子量: 313.24
• MDL番号: MFCD00012233
• UNSPSCコード: 12352103
• PubChem Substance ID: 24864583
• NACRES: NA.22

特性

• 品質水準: 100
• 反応適合性: reaction type: Grignard Reaction
• 濃度: 0.5 M in THF
• bp: 67 °C
• 密度: 0.906 g/mL at 25 °C
• SMILES記法: CCCCCCCCCCCCCCCCCC[Mg]Cl
• InChI: 1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
• InChI Key: ONJPXWZQVLKGIU-UHFFFAOYSA-M

詳細

詳細

Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.

アプリケーション

Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H302,H314,H335,H351
• 注意書き: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH014,EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 1
• 引火点(°F): -4.0 °F - closed cup
• 引火点(℃): -20 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter