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71853

Sigma-Aldrich

Sodium perchlorate monohydrate

puriss. p.a., ACS reagent, ≥98.0% (T)

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About This Item

Linear Formula:
NaClO4 · H2O
CAS Number:
7791-07-3
Molecular Weight:
140.46
EC Number:
231-511-9
MDL number:
MFCD00149164
UNSPSC Code:
12352300
PubChem Substance ID:
329763586
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

200

Assay

≥98.0% (T)

form

powder, crystals or chunks

impurities

≤0.0005% total nitrogen (N)

pH

6.0-8.0 (25 °C, 50 mg/mL in H2O)

anion traces

chloride (Cl-): ≤30 mg/kg
sulfate (SO42-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤3 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

O.[Na+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1

InChI key

IXGNPUSUVRTQGW-UHFFFAOYSA-M

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General description

Sodium perchlorate monohydrate (NaClO4· H2O) is a hydrated sodium salt. Its crystal structure has been investigated by three-dimensional single crystal x-ray diffraction studies. Its crystals belong to the monoclinic crystal system having space group C2/c.

Application

Sodium perchlorate monohydrate (NaClO4· H2O) may be used in the preparation of 0.01M NaClO4 solution. This solution was employed in oxalate adsorption isotherm experiments.
Sodium perchlorate monohydrate has been used as a component of ion exchange (IE) buffer A and B for the purification of RNA using IE-high-performance liquid chromatography (HPLC).

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Danger

Hazard Statements

H271 - H302 - H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Oxidizing solids
Perchlorates
Hazardous rank III
3rd oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

Certificates of Analysis (COA)

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Dissolution mechanisms of goethite in the presence of siderophores and organic acids.
Reichard PU, et al.
Geochimica et Cosmochimica Acta, 71(23), 5635-5650 (2007)
Hydrogen bond studies. CII. An X-ray determination of the crystal structure of sodium perchlorate monohydrate, NaClO4. H2O.
Berglund B, et al.
Acta Crystallographica Section B, Structural Science, 31(7), 1842-1846 (1975)
Deniz Ucar et al.
Environmental technology, 37(2), 183-191 (2015-06-24)
Nitrate and perchlorate were identified as significant water contaminants all over the world. This study aims at evaluating the performances of the heterotrophic-autotrophic sequential denitrification process for reductive nitrate and perchlorate removal from drinking water. The reduced nitrate concentration in
Christopher Polonyi et al.
Dalton transactions (Cambridge, England : 2003), 43(31), 11941-11949 (2014-06-27)
The ability of the anticancer active drug cisplatin to exert biological activity through interference with nucleic acid function is well documented. Since kinetics play a key role in determining product distributions in these systems, methods for accurate documentation of reactivity
Ana Vemić et al.
Journal of pharmaceutical and biomedical analysis, 102, 314-320 (2014-12-03)
The aim of this paper is to present a development of liquid chromatographic method when chaotropic salts are used as mobile phase additives following the QbD principles. The effect of critical process parameters (column chemistry, salt nature and concentration, acetonitrile
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