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255572

Sigma-Aldrich

Potassium chlorate

ACS reagent, ≥99.0%

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About This Item

Linear Formula:
KClO3
CAS Number:
Molecular Weight:
122.55
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24
Assay:
≥99.0%
grade:
ACS reagent
form:
crystalline powder

grade

ACS reagent

Quality Level

Assay

≥99.0%

form

crystalline powder

impurities

≤0.001% N compounds
≤0.005% insolubles

pH

5-6.5 (25 °C, 61.3 g/L)

mp

356 °C (lit.)

anion traces

bromate (BrO3-): ≤0.015%
chloride (Cl-): ≤0.001%
sulfate (SO42-): passes test

cation traces

Ca: ≤0.002%
Fe: ≤3 ppm
Mg: ≤0.002%
Na: ≤0.01%
heavy metals: ≤5 ppm (by ICP)

SMILES string

[K+].[O-]Cl(=O)=O

InChI

1S/ClHO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1

InChI key

VKJKEPKFPUWCAS-UHFFFAOYSA-M

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General description

Potassium chlorate (KClO3) is widely used in the chemical industry as an oxidizing agent. KCIO3 is used in the conversion of alcohols to corresponding aldehyde or ketone derivatives.

Application

Potassium chlorate is used:
  • In the sequential extraction (SEP) of selenium to analyze its isotopic composition from various Se pools.
  • In the preparation of graphite oxide (GO).

Pictograms

Flame over circleSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Ox. Sol. 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

FSL

Group 1: Oxidizing solids
Chlorates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

255572-BULK:
255572-5G:4548173252483
255572-VAR:
255572-500G:4548173125329
255572-100G:4548173125312


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Carbon fragments are ripped off from graphite oxide sheets during their thermal reduction.
Jankovsky O, et al.
New. J. Chem., 38(12), 5700-5705 (2014)
The Decomposition of Solid Potassium Chlorate by X Rays.
Heal HG.
Canadian Journal of Chemistry, 37(5), 979-987 (1959)
Single sheet functionalized graphene by oxidation and thermal expansion of graphite.
McAllister MJ, et al.
Chemistry of Materials, 19(18), 4396-4404 (2007)
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Chemical Society reviews, 39(1), 228-240 (2009-12-22)
The chemistry of graphene oxide is discussed in this critical review. Particular emphasis is directed toward the synthesis of graphene oxide, as well as its structure. Graphene oxide as a substrate for a variety of chemical transformations, including its reduction

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