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Safety Information

13020

Sigma-Aldrich

Lithium hydroxide monohydrate

purum, ≥98.5%

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About This Item

Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
Assay:
≥98.5%
form:
crystalline

grade

purum

Quality Level

Assay

≥98.5%

form

crystalline

impurities

≤1% Li2CO3

pH

12 (0.4 g/L)

anion traces

chloride (Cl-): ≤500 mg/kg
sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤500 mg/kg
Fe: ≤10 mg/kg
K: ≤200 mg/kg
Na: ≤200 mg/kg

SMILES string

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

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General description

Lithium hydroxide monohydrate is a hydrate of alkali metal hydroxide. Its IR spectral analysis has been reported. A refinement of its crystal structure has been described. Its crystals exhibit monoclinic crystal system and C2/m space group. It can be prepared by reacting Li metal with H2O, followed by the evaporation of the aqueous solution.

Application

Lithium hydroxide monohydrate (LiOH.H2O) may be employed as a catalyst during the melt transesterification of diphenyl carbonate and bisphenol A. Kinetics of this transesterification reaction have been investigated.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

13020-VAR:
13020-6X500G:
13020-100G:
13020-6X100G:
13020S-25KG:
13020-500G:
13020-100KG:
13020-BULK:
13020-1KG:
13020-6X1KG:


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Hydrogen bonding. VI. Structural and infrared spectral analysis of lithium hydroxide monohydrate and cesium and rubidium hydroxide hydrates.
Gennick I and Harmon KM.
Inorganic Chemistry, 14(9), 2214-2219 (1975)
Infrared active vibrational modes of lithium hydroxide monohydrate.
Hase Y.
Inorganic and Nuclear Chemistry Letters, 16(3), 159-163 (1980)
Kinetics of melt transesterification of diphenyl carbonate and bisphenol A to polycarbonate with lithium hydroxide monohydrate catalyst.
Kim Y, et al.
Industrial & Engineering Chemistry Research, 31(9), 2118-2127 (1992)
Refinement of the crystal structure of lithium hydroxide monohydrate.
Alcock NW.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 27(8), 1682-1683 (1971)
Maria Concetta Bruzzoniti et al.
Journal of chromatography. A, 1187(1-2), 188-196 (2008-02-29)
A new high performance ion chromatographic method has been developed for the separation of the nine chlorinated-brominated haloacetic acids (HAAs) that are the disinfection by-products of chlorination of drinking water, using a macrocycle-based adjustable-capacity anion-exchange separator column (IonPac Cryptand A1).

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