936790

meCgPPh Pd G3 ChemBeads

• Synonym(s): [(1,3,5,7-Tetramethyl-6-phenyl-2,4,6-trioxa-6-phosphaadamantane)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
• Empirical Formula (Hill Notation): C₂₉H₃₄NO₆PPdS
• CAS Number: 2230788-58-4
• Molecular Weight: 662.04
• UNSPSC Code: 12352100
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• composition: , ~5 wt. % (loading of catalyst)
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• SMILES string: CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC34CC5(C)OC(C)(CC(C)(O3)P5c6ccccc6)O4
• InChI: 1S/C16H21O3P.C12H10N.CH4O3S.Pd/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h5-9H,10-11H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
• InChI key: PBZIJOKKZYPPSJ-UHFFFAOYSA-M

Description

General description

[(1,3,5,7-Tetramethyl-6-phenyl-2,4,6-trioxa-6-phosphaadamantane)-2-(2′-amino-1,1′-biphenyl)]palladium (II) methanesulfonate (meCgPPh Pd G3) is an air and moisture sensitive palladium compound used as a catalyst in cross coupling reaction.

Application

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For larger scale uses, product also available in powdered form (762822)

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable