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Safety Information

90179

Supelco

Morpholine

analytical standard

Synonym(s):

Tetrahydro-1,4-oxazine

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About This Item

Empirical Formula (Hill Notation):
C4H9NO
CAS Number:
Molecular Weight:
87.12
Beilstein:
102549
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

3 (vs air)

vapor pressure

31 mmHg ( 38 °C)
7 mmHg ( 20 °C)

Assay

≥99.5% (GC)

autoignition temp.

590 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

10.8 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.454 (lit.)
n20/D 1.455

bp

129 °C (lit.)

mp

−7-−5 °C (lit.)

density

1.000 g/mL at 20 °C
0.996 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

C1COCCN1

InChI

1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2

InChI key

YNAVUWVOSKDBBP-UHFFFAOYSA-N

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General description

Morpholines are systemic compounds that exert both protective and curative actions against fungal diseases.

Application

Morpholine has been used as a reference standard for the identification of the analyte in water by gas chromatography-mass spectrometry (GC-MS). It may be used as a reference standard for the determination of the analyte in fruit-based soft drinks, in natural waters and in vegetables by liquid chromatography-mass spectrometry (LC-MS) and in drugs by GC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

87.8 °F - closed cup

Flash Point(C)

31 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

90179-5ML-F:4548173362182
90179-BULK-F:
90179-VAR-F:
90179-10ML-F:4548173362175


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Analytical method validation for the evaluation of cutaneous occupational exposure to different chemical classes of pesticides
Simonelli A, et al.
Journal of Chromatography. B, Biomedical Applications, 860(1), 26-33 (2007)
Multi-residue determination of pesticides in fruit-based soft drinks by fast liquid chromatography time-of-flight mass spectrometry
Gilbert-Lopez B, et al.
Talanta, 81(4-5), 1310-1321 (2010)
Development of a Method for Rapid Determination of Morpholine in Juices and Drugs by Gas Chromatography-Mass Spectrometry
Cao M, et al.
Journal of Analytical Methods in Chemistry, 2018(2), 161-169 (2018)
Metabolic pathways of agrochemicals: insecticides and fungicides
Metabolic Pathways of Agrochemicals: Herbicides and Plant Growth Regulators, 1 (1998)
Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables.
Sannino A, et al.
Journal of Chromatography A, 1036(2), 161-169 (2004)

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