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45643

Supelco

Propineb

PESTANAL®, analytical standard

Synonym(s):

Zinc propylenebis(dithiocarbamate)

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About This Item

Linear Formula:
[C5H8N2S4Zn]n
CAS Number:
12071-83-9
Beilstein:
2360676
EC Number:
235-134-0
MDL number:
MFCD16661267
UNSPSC Code:
41116107
PubChem Substance ID:
329756857
NACRES:
NA.24

grade

analytical standard

Quality Level

100

description

technical mixture

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

mol wt

Mw 289.78 g/mol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC1CNC(=S)S[Zn]SC(=S)N1

InChI

1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2

InChI key

KKMLIVYBGSAJPM-UHFFFAOYSA-L

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General description

Propineb belongs to the dithiocarbamates (DTCs) class of fungicides, widely used in agriculture and horticulture. It has an additional advantage of low production cost, broad-spectrum of chemical and biological reactivity.

Application

Propineb may be used as an analytical reference standard for the quantification of the analyte in environmental samples and vegetable samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment
GHS08,GHS09

Signal Word

Warning

Hazard Statements

H373 - H411

Precautionary Statements

P260 - P273 - P314 - P391 - P501

Hazard Classifications

Aquatic Chronic 2 - STOT RE 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

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Certificates of Analysis (COA)

Lot/Batch Number
BCBT5765
BCBX5669
BCBT9583
SZBD294XV
SZBA033XV

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Marina Marinovich et al.
Chemical research in toxicology, 15(1), 26-32 (2002-01-22)
Dithiocarbamates (DTCs) are used mainly in agriculture as pesticides and as alcohol deterrent drugs. Neurological complications as well as movement disorders characterized by plastic rigidity, muscle twitch and paralysis are the prevailing symptoms in chronically exposed animals and humans. We
A T Wojdyła
Communications in agricultural and applied biological sciences, 69(4), 705-715 (2005-03-11)
Chitosan, (Biochikol 020 PC) a potential elicitor of plant defence and also an active inhibitor of fungal growth was used in experiments. The compound was used at concentrations 0.01 to 0.2% as a plant spray for rose protection against Sphaerotheca
M Yaldiz et al.
Clinical and experimental obstetrics & gynecology, 27(3-4), 235-237 (2001-02-24)
The dithiocarbamates are known to cause dermatitis, conjunctivitis, rhinitis, pharyngitis and bronchitis in humans. The experimental group received Propineb (obtained from Bayer) concentrations of 400 ppm in distilled water five days a week (treatment time three weeks) administered orally by
Kelly Flampouri et al.
Talanta, 80(5), 1799-1804 (2010-02-16)
Two of the most important categories of pesticides used in agricultural practice are organophosphates and dithiocarbamates. Their extensive and inappropriate use has rendered their reliable monitoring at trace levels more and more necessary. This study presents the construction of a
E Deveci et al.
The Journal of toxicological sciences, 24(2), 79-85 (1999-06-01)
Dithiocarbamate propineb and maneb are organometal fungicides, which are widely used for the control of diseases in plants. Female Wistar rats were exposed orally to 200 and 400 ppm propineb (Zn-containing dithiocarbamate) and 250 ppm maneb (Mn-containing dithiocarbamate), from the
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