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431400

Supelco

Phosphomolybdic acid hydrate

≥99.99% trace metals basis

Synonym(s):

Molybdophosphoric acid

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About This Item

Linear Formula:
H3[P(Mo3O10)4] · xH2O
CAS Number:
Molecular Weight:
1825.25 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.21

Quality Level

Assay

≥99.99% trace metals basis

form

crystals

reaction suitability

reagent type: oxidant

impurities

≤0.01% insolubles
<100 ppm total metallic impurities

density

1.62 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.02%
sulfate (SO42-): ≤0.025%

cation traces

Ca: ≤0.02%
Fe: ≤0.005%
NH4+: ≤0.01%
heavy metals: ≤0.005%

SMILES string

O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O

InChI

1S/12Mo.H3O4P.H2O.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;

InChI key

PDDXOPNEMCREGN-UHFFFAOYSA-N

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General description

Phosphomolybdic acid hydrate is a heteropolyacid hydrate. It participates in the synthesis of molybdenum disulfide (MoS2)-reduced graphene oxide (RGO) composites. Phosphomolybdic acid is one of the components of the Goldner′s trichrome stain used for tissue staining.

Application

Employed in preparation of a hybrid organic-inorganic, electroactive material with potential application as a cation-insertion electrode in batteries.
Reactant for preparation of:
  • Catalysts for the nitration of aromatic compounds
  • Highly dispersed MoOx/CNTs (carbon nanotubes) as a support for Pt catalysts
  • Reduced molybdophosphate mixed-valence Keggin clusters
  • Polyoxometalate (POM) hybrid materials based on Keggin polyanion building blocks
  • Luminescent Langmuir-Blodgett films
  • Anchored Wilkinson catalyst
A precursor to hybrid organic-inorganic based molecular batteries with applications as cation-insertion electrodes.

Features and Benefits

Meets A.C.S. reagent specifications.

Pictograms

Flame over circleCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Ox. Sol. 3 - Skin Corr. 1B

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

431400-10G:4548173960784
431400-BULK:
431400-50G:4548173960791
431400-VAR:


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Liu, H.-Y.; et al.
Crystal Growth & Design, 11, 1786-1786 (2011)
Tanielyan, S. K.; et al.
ACS Catalysis, 1, 159-159 (2011)
Liu, L.; et al.
Journal of Organometallic Chemistry, 696, 1319-1319 (2011)
Zhi Ming Cui et al.
Chemical communications (Cambridge, England), 47(29), 8418-8420 (2011-06-28)
HPMo self-assembly on carbon nanotubes followed by decomposition is used to fabricate highly dispersed MoO(x)/CNTs as a support for high performance of a Pt catalyst towards methanol oxidation.
Tomoyuki Akutagawa et al.
Inorganic chemistry, 50(14), 6711-6718 (2011-06-16)
Hydrogen-bonded assemblies of the two-electron reduced mixed-valence Keggin clusters [PMo(12)O(40)](5-) and [SiMo(12)O(40)](6-) were obtained by the one-pot electron-transfer reactions between p-phenylenediamine (PPD) or 2,3,5,6-tetramethyl-PPD (TMPPD) (donors) and H(+)(3)[PMo(12)O(40)](3-) or H(+)(4)[SiMo(12)O(40)](4-) (acceptors) in CH(3)CN. The redox states of the [PMo(12)O(40)](5-) and

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