34885-M

Methanol

≥99.9%, gradient grade, suitable for HPLC

• Synonym(s): Methyl alcohol
• Linear Formula: CH₃OH
• CAS Number: 67-56-1
• Molecular Weight: 32.04
• Beilstein: 1098229
• EC Number: 200-659-6
• MDL number: MFCD00004595
• UNSPSC Code: 15101803
• PubChem Substance ID: 329755085
• NACRES: NA.05

Properties

• product name: Methanol, suitable for HPLC, gradient grade, ≥99.9%
• grade: gradient grade
• vapor density: 1.11 (vs air)
• vapor pressure: 410 mmHg ( 50 °C); 97.68 mmHg ( 20 °C)
• Assay: ≥99.9%
• form: liquid
• autoignition temp.: 725 °F
• expl. lim.: 36 %
• technique(s): HPLC: suitable
• impurities: KMnO₄ red. matter (as O), in accordance; ≤0.0005% free alkali (as NH₃); ≤0.0005% non-volatile matter; ≤0.001% acetaldehyde; ≤0.001% acetone (GC); ≤0.001% formaldehyde; ≤0.02% water (Karl Fischer); ≤1 ppb fluorescence (quinine) at 254 nm; ≤1 ppb fluorescence (quinine) at 365nm
• evapn. residue: <0.0003%
• color: APHA: ≤10
• refractive index: n20/D 1.329 (lit.)
• bp: 64.7 °C (lit.)
• mp: −98 °C (lit.)
• density: 0.791 g/mL at 25 °C (lit.)
• HPLC-gradient: ≤2 mAU at 230 nm; ≤5 mAU at 254 nm
• absorption: in accordance
• UV absorption: λ: 210 nm A_max: 0.50; λ: 220 nm A_max: 0.30; λ: 230 nm A_max: 0.15; λ: 235 nm A_max: 0.10; λ: 240 nm A_max: 0.05; λ: 260 nm A_max: 0.01; λ: 400 nm A_max: 0.01
• format: neat
• SMILES string: CO
• InChI: 1S/CH4O/c1-2/h2H,1H3
• InChI key: OKKJLVBELUTLKV-UHFFFAOYSA-N

Description

General description

Thermochemical conversion of methanol to C₂-C₁₀ hydrocarbons in the presence of shape-selective zeolites has been reported. Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.

Application

Methanol (MeOH) has been used as an eluent in the HPLC estimation of malondialdehyde in plasma, which is an indicator of oxidative stress.
It may be used in the following studies:

• Colony forming unit-fibroblast assay of bone marrow mononuclear cells.
• As solvent for the preparation of extracts of hyphae of Aspergillus for the estimation of gliotoxin by reversed phase-HPLC.
• Immunofluorescence studies.
• To compose eluent for the ion-pair reverse-phase HPLC isolation of nucleotides and their decomposition products.

Packaging

View returnable container options.

Preparation Note

Product filtered through a 0.2 μm filter

Other Notes

Pure-Pac^® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

Important notice

• The article number 34885-6X1L-M will be discontinued. Please order the single bottle 34885-1L-M which is physically identical with the same exact specifications.

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Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS02,GHS06,GHS08
• Signal Word: Danger
• Hazard Statements: H225,H301 + H311 + H331,H370
• Precautionary Statements: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
• Target Organs: Eyes,Central nervous system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): 49.5 °F - closed cup
• Flash Point(C): 9.7 °C - closed cup