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Safety Information

33977

Supelco

Foramsulfuron

PESTANAL®, analytical standard

Synonym(s):

2-[3-(4,6-Dimethoxy-2-pyrimidinyl)ureidosulfonyl]-4-(formamido)-N,N-dimethylbenzamide

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About This Item

Empirical Formula (Hill Notation):
C17H20N6O7S
CAS Number:
173159-57-4
Molecular Weight:
452.44
MDL number:
MFCD04972564
UNSPSC Code:
41116107
PubChem Substance ID:
329754717
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

[H]C(=O)Nc1ccc(C(=O)N(C)C)c(c1)S(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2

InChI

1S/C17H20N6O7S/c1-23(2)15(25)11-6-5-10(18-9-24)7-12(11)31(27,28)22-17(26)21-16-19-13(29-3)8-14(20-16)30-4/h5-9H,1-4H3,(H,18,24)(H2,19,20,21,22,26)

InChI key

PXDNXJSDGQBLKS-UHFFFAOYSA-N

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General description

Foramsulfuron is a sulfonylurea herbicide used in controlling a wide spectrum of weeds. Its mode of action involves inhibiting the enzyme activity of acetolactate synthase (ALS) which is involved in biosynthesis of branched amino acids.

Application

Foramsulfuron may be used as a reference standard for the determination of foramsulfuron in water samples by solid-phase extraction and liquid chromatography-tandem mass spectrometry (SPE-LC-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

33977-VAR-R:
33977-100MG-R:
33977-BULK-R:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD9709
BCCD4053
BCBT5471
BCBT5107
SZBF091XV

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James T Brosnan et al.
Planta, 243(1), 149-159 (2015-09-12)
This is a first report of an Ala-205-Phe substitution in acetolactate synthase conferring resistance to imidazolinone, sulfonylurea, triazolopyrimidines, sulfonylamino-carbonyl-triazolinones, and pyrimidinyl (thio) benzoate herbicides. Resistance to acetolactate synthase (ALS) and photosystem II inhibiting herbicides was confirmed in a population of
Photooxidation of foramsulfuron: Effects of char substances.
Vittoria PM, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 326, 16-20 (2016)
Trace analysis of sulfonylurea herbicides in water samples by solid-phase extraction and liquid chromatography-tandem mass spectrometry.
Fenoll J
Talanta, 101, 273-282 (2012)
Amit Paporisch et al.
Pesticide biochemistry and physiology, 138, 22-28 (2017-05-01)
Three sweet corn genotypes, two inbred lines (IBER001 and IBER002) and their hybrid (ER00X), differ in their phenotypic responses to several P450-metabolized herbicides, used in sweet corn, namely, foramsulfuron, iodosulfuron, rimsulfuron and tembotrione. Foramsulfuron is a sulfonylurea herbicide commonly formulated
Maykel Hernández-Mesa et al.
Journal of chromatography. A, 1617, 460831-460831 (2020-01-18)
This work proposes a novel Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method in combination with ultra-high performance liquid chromatography-tandem mass spectrometry for the determination of sulfonylurea residues in edible seeds. The chromatographic separation of nine sulfonylureas was accomplished

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