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Key Documents

Safety Information

33400

Supelco

Bromophos-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C8H8BrCl2O3PS
CAS Number:
Molecular Weight:
366.00
Beilstein:
1988276
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

mp

53-56 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

COP(=S)(OC)Oc1cc(Cl)c(Br)cc1Cl

InChI

1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H3

InChI key

NYQDCVLCJXRDSK-UHFFFAOYSA-N

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General description

Bromophos-methyl is an organophosphorus insecticide widely used to control a wide variety of insects in agriculture and forestry sector.

Application

Bromophos-methyl may be used as a reference standard for the determination of bromophos-methyl in biological samples using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Bromophos-methyl may be used as a reference standard for the determination of the insecticidel in berries using head-space solid phase microextraction with gas chromatography coupled to mass spectrometry (SPME-GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

33400-100MG:
33400-BULK:
33400-VAR:


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An analytical method for the rapid screening of organophosphate pesticides in human biological samples and foodstuffs.
Tarbah AF, et al.
Forensic Science International, 121(1-2), 126-133 (2001)
Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries.
Lambropoulou AD and Albanis AT
Journal of Chromatography A, 993(1-2), 197-203 (2003)
Simple determination of 22 organophosphorous pesticides in human blood using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Musshoff F, et al.
Journal of Chromatographic Science, 40(1), 29-39 (2002)
C Köppel et al.
Journal of toxicology. Clinical toxicology, 29(2), 203-207 (1991-01-01)
One hour after suicidal ingestion of about 20 mL of a 38% solution of bromofosmethyl, CAS: 2104-96-3 (bromophos), a 52 year-old female was admitted to the hospital with extreme miosis, hypersalivation, hyperperistalsis and muscular fibrillation. Gastric lavage was performed and
J L Willems et al.
Archives of toxicology, 67(2), 79-84 (1993-01-01)
We measured in nine patients, poisoned by organophosphorus agents (ethyl parathion, ethyl and methyl parathion, dimethoate, or bromophos), erythrocyte and serum cholinesterase activities, and plasma concentrations of the organophosphorus agent. These patients were treated with pralidoxime methylsulphate (Contrathion), administered as

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