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Safety Information

30-2840

Sigma-Aldrich

Titanium(IV) butoxide

CP

Synonym(s):

Orthotitanic acid tetrabutylester, TNBT, TYZOR® TBT organic titanate, Tetrabutyl orthotitanate, Tetrabutyl titanate

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About This Item

Linear Formula:
Ti(OCH2CH2CH2CH3)4
CAS Number:
5593-70-4
Molecular Weight:
340.32
Beilstein:
4148236
MDL number:
MFCD00009433
UNSPSC Code:
12352303
PubChem Substance ID:
329753450

grade

CP

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

availability

available only in Japan

refractive index

n20/D 1.491 (lit.)

bp

206 °C/10 mmHg (lit.)

density

1.00 g/mL at 20 °C (lit.)

storage temp.

15-25°C

SMILES string

CCCCO[Ti](OCCCC)(OCCCC)OCCCC

InChI

1S/4C4H9O.Ti/c4*1-2-3-4-5;/h4*2-4H2,1H3;/q4*-1;+4

InChI key

YHWCPXVTRSHPNY-UHFFFAOYSA-N

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Application

Used to prepare nanosized titania in the anatase form and ferroelectric Bi4Ti3O12 thin films. Used in the preparation of nanocrystalline TiO2 powders at room temperature.

Legal Information

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

Signal Word

Danger

Hazard Statements

H226,H315,H318,H335,H336

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

136.8 °F

Flash Point(C)

58.2 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

30-2840-5-500G-J:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Huaqiang Zhuang et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 16(7), 1352-1355 (2015-02-26)
Ternary core-shell heterostructured rutile@anatase@Crx Oy nanorod arrays were elaborately designed as photoanodes for efficient photoelectrochemical water splitting under visible-light illumination. The four-fold enhanced and stabilized visible-light photocurrent highlights the unique role of the interim anatase layer in accelerating the interfacial
Jun-Bing Fan et al.
Chemical communications (Cambridge, England), 46(31), 5805-5807 (2010-07-01)
A low cost and environmentally benign process for tetrabutyl titanate-controlled ring-opening polymerization of epsilon-caprolactone at ambient temperature of 10-40 degrees C is introduced affording poly(epsilon-caprolactone) with pre-designed molecular weights and narrow molecular weight distribution.
S Anantharaj et al.
Biomacromolecules, 13(8), 2446-2455 (2012-06-21)
A new dual ester-urethane melt condensation methodology for biological monomers-amino acids was developed to synthesize new classes of thermoplastic polymers under eco-friendly and solvent-free polymerization approach. Naturally abundant L-amino acids were converted into dual functional ester-urethane monomers by tailor-made synthetic
Jun Lu et al.
Nature communications, 5, 5693-5693 (2014-12-17)
The capacity fade of lithium manganate-based cells is associated with the dissolution of Mn from cathode/electrolyte interface due to the disproportionation reaction of Mn(III), and the subsequent deposition of Mn(II) on the anode. Suppressing the dissolution of Mn from the
Mukesh K Sharma et al.
Biosensors & bioelectronics, 74, 299-304 (2015-07-08)
Bacillus anthracis is a bioterrorism agent classified by the Centers for Disease Control and Prevention (CDC). Herein, a novel electrochemical immunosensor for the sensitive, specific and easy detection of anthrax protective antigen (PA) toxin in picogram concentration was developed. The
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