8.01081
Aluminium chloride
anhydrous powder sublimed for synthesis
Synonym(s):
Aluminium chloride, Hydrochloric acid aluminium salt anhydrous, Trichloroaluminum
About This Item
synthesis grade
grade
for synthesis
synthesis grade
Quality Level
vapor pressure
1 hPa ( 20 °C)
form
powder
potency
3450 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rabbit)
pH
2.4 (20 °C, 100 g/L in H2O)
mp
180-181 °C (sublimed)
solubility
450 g/L (decomposition)
density
1.31 g/cm3 at 200 °C (liquid)
bulk density
1200 kg/m3
storage temp.
2-30°C
SMILES string
[Al+3].[Cl-].[Cl-].[Cl-]
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VSCWAEJMTAWNJL-UHFFFAOYSA-K
General description
Application
- In Friedel−Crafts reactions.
- In the carboxymethylation of alcohols in the presence of dimethyl carbonate.
- To synthesize a porous organic polymer with hydroxyquinoline via polymerization reaction between perylene, 8-hydroxyquinoline, and chloroform.
It is also used in combination with NaI or KI in acetonitrile for varieties organic transformations such as Claisen rearrangement of aromatic alcohols, selective dealkylation aliphatic methyl ether, and chemoselective C−O bond cleavage of esters, acetals, ethers, and oxathiolanes.
Linkage
Analysis Note
Identity (ICP-OES): passes test
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
PDSCL
Deleterious substance
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
8010818889:
8010810251:
8010810000:
8010810100:
IN2RCMA801081:
8010810500:
8010812500:
8010811000:
8010810252:
8010819050:
8010819999:
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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