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Safety Information

1.04003

Sigma-Aldrich

Formaldehyde solution about 37%

GR for analysis stabilized with about 10% methanol ACS,Reag. Ph Eur

Synonym(s):

Formaldehyde solution, Formaline solution, Methanal solution, Methylaldehyde solution, Formalin

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About This Item

Linear Formula:
HCHO
CAS Number:
Molecular Weight:
30.03
Beilstein:
1209228
MDL number:
UNSPSC Code:
12352114
NACRES:
NA.21

grade

ACS reagent

Quality Level

Agency

reag. Ph. Eur.

vapor density

1.03 (vs air)

vapor pressure

52 mmHg ( 37 °C)

form

liquid

autoignition temp.

300 °C (Formaldehyde)
572 °F

expl. lim.

7-73 % (v/v) Formaldehyde)

concentration

36.5-38.0% (iodometric, acidimetric)

pH

2.8-4.0 (20 °C in H2O)

bp

93-96 °C/1013 hPa

mp

<-15 °C

transition temp

flash point 62 °C (Formaldehyde)

density

1.09 g/cm3 at 20 °C
1.09 g/mL at 25 °C (lit.)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

15-25°C

SMILES string

[H]C([H])=O

InChI

1S/CH2O/c1-2/h1H2

InChI key

WSFSSNUMVMOOMR-UHFFFAOYSA-N

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General description

Formaldehyde (HCOH) is one of the most familiar and effective fixatives. The fixation of the histological specimen material of human or animal origin is commonly performed in a 4% or 10% Formaldehyde solution. Chemically, the 4 % Formaldehyde solution equals a 10 % Formalin solution.

Analysis Note

Assay (acidimetric): 36.5 - 38.0 %
Assay (iodometric): 36.5 - 38.0 %
Identity: passes test
Color: ≤ 10 Hazen
Appearance of solution: passes test
Free acid (as HCOOH): ≤ 0.025 %
Density (20 °C): 1.080 - 1.090 g/ml
Chloride (Cl): ≤ 0.0001 %
Sulfate (SO₄): ≤ 0.002 %
Heavy metals (as Pb): ≤ 0.0002 %
Fe (Iron): ≤ 0.0001 %
Methanol (GC): 9.0 - 11.0 %
Sulfated ash: ≤ 0.002 %

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 1 - STOT SE 3

Target Organs

Eyes,Central nervous system, Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

143.6 °F - closed cup

Flash Point(C)

62 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Specified Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

1040035000:
NAPE1040032500-E1L:
1040039180:
1040039025:
1040031000:
1040032500:
1040030000:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Protocols

Preparation of a standard solution for Formaldehyde

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