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Safety Information

T58009

Sigma-Aldrich

Tridecylamine

98%

Synonym(s):

1-Aminotridecane

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About This Item

Linear Formula:
CH3(CH2)12NH2
CAS Number:
Molecular Weight:
199.38
Beilstein:
1739990
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

bp

265 °C (lit.)

mp

30-32 °C (lit.)

SMILES string

CCCCCCCCCCCCCN

InChI

1S/C13H29N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14/h2-14H2,1H3

InChI key

ABVVEAHYODGCLZ-UHFFFAOYSA-N

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Application

Tridecylamine can undergo:
  • Dehydrogenation to nitriles catalyzed by ruthenium complex.
  • Aerobic oxidation to carbonyl compounds catalyzed by vitamin C and Cu complex.

Tridecylamine is generally used in introducing C13 chain to the substrate. Some of the application are:
  • Synthesis of alkylated 1,2,4-triazoles as bridging ligand in the preparation of polymeric 1-dimensional chains of iron(II) species.
  • Synthesis of amphiphiles such as N-tridecyl-β-hydroxypropionic acid amide (THPA) and N-(β-hydroxyethyl)tridecanoic acid amide (HETA).
  • As a ligand in the preparation of palladium-based catalyst, [PdCl2(TDA)2].

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

T58009-5G:
T58009-25G:
T58009-BULK:
T58009-VAR:


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Copper/ascorbic acid dyad as a catalytic system for selective aerobic oxidation of amines
Srogl J and Voltrova S
Organic Letters, 11(4), 843-845 (2009)
Double Dehydrogenation of Primary Amines to Nitriles by a Ruthenium Complex Featuring Pyrazole Functionality
Dutta I, et al.
Journal of the American Chemical Society, 140(28), 8662-8666 (2018)
Spin-transition behaviour in chains of Fe II bridged by 4-substituted 1, 2, 4-triazoles carrying alkyl tails,.
Roubeau O, et al.
New. J. Chem., 25(1), 144-150 (2001)
Catalytic investigation of PdCl2 (TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction.
Mastalir A, et al.
Reaction Kinetics, Mechanisms and Catalysis, 113(1), 61-68 (2014)
1-Heptyne semihydrogenation catalized by palladium or rhodium complexes: Influence of: metal atom, ligands and the homo/heterogeneous condition.
Quiroga M E, et al.
Applied Catalysis A: General, 326(2), 121-129 (2007)

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