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Safety Information

M50850

Sigma-Aldrich

2-Methylimidazole

99%

Synonym(s):

2-Methylglyoxaline

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About This Item

Empirical Formula (Hill Notation):
C4H6N2
CAS Number:
Molecular Weight:
82.10
Beilstein:
1368
EC Number:
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

<1 mmHg ( 0 °C)

Quality Level

Assay

99%

bp

267-268 °C (lit.)

mp

142-143 °C (lit.)

SMILES string

Cc1ncc[nH]1

InChI

1S/C4H6N2/c1-4-5-2-3-6-4/h2-3H,1H3,(H,5,6)

InChI key

LXBGSDVWAMZHDD-UHFFFAOYSA-N

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Application

2-Methylimidazole can be used as:      
  • A coordination regulator to fabricate 2D metal-organic framework-5 (MOF-5) nanosheet, which is used as an efficient catalyst for Knoevenagel condensation reaction.      
  • An alkaline inducer in the synthesis of amorphous FeCoNi ternary hydroxide nanosheets applicable as an active electrocatalyst for oxygen evolution reaction.      
  • A solvent system in combination with water to synthesize zeolitic imidazolate frameworks-8 (ZIF-8) membrane for the potential application in gas separation.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1C

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

M50850-100G:
M50850-5G:
M50850-BULK:
M50850-10KG:
M50850-VAR:
M50850-500G:


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Kyo Sung Park et al.
Proceedings of the National Academy of Sciences of the United States of America, 103(27), 10186-10191 (2006-06-27)
Twelve zeolitic imidazolate frameworks (ZIFs; termed ZIF-1 to -12) have been synthesized as crystals by copolymerization of either Zn(II) (ZIF-1 to -4, -6 to -8, and -10 to -11) or Co(II) (ZIF-9 and -12) with imidazolate-type links. The ZIF crystal
Reda M Abdelhameed et al.
Journal of colloid and interface science, 552, 494-505 (2019-06-04)
Removal of naphthols, as one of the most common pharmaceutical intermediates which released in the wastewater, is in the top priority for the time being. In the current study, zeolitic imidazole frameworks (ZIF-8, Zn & ZIF-67, Co) were directly prepared
Po-Hsun Huang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(19), 1900913-1900913 (2019-10-09)
Synthesis of nanoparticles and particulate nanomaterials with tailored properties is a central step toward many applications ranging from energy conversion and imaging/display to biosensing and nanomedicine. While existing microfluidics-based synthesis methods offer precise control over the synthesis process, most of
Jianfeng Li et al.
Inorganic chemistry, 49(5), 2398-2406 (2010-01-29)
The X-ray characterization of the five-coordinate picket-fence porphyrin complex, [Co(TpivPP)(2-MeHIm)], is reported. The complex has the displacement of cobalt from the porphyrin plane = 0.15 A, and Co-N(Im) = 2.145(3) and (Co-N(p))(av) = 1.979(3) A. This five-coordinate complex, in the
Kiriaki Pegklidou et al.
Journal of agricultural and food chemistry, 56(12), 4482-4490 (2008-05-23)
The potential role of 2-methyl imidazole in improving lycopene production by Blakeslea trispora with regards to yield, selectivity, and safety aspects was investigated in batch culture. Optimization of the bioprocess conditions in terms of (a) (+) and (-) strain ratio

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