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Safety Information

ALD00002

Sigma-Aldrich

Li-Quinoline Ligand

Synonym(s):

3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline

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About This Item

Empirical Formula (Hill Notation):
C14H15NO
CAS Number:
151657-37-3
Molecular Weight:
213.28
MDL number:
MFCD28053559
UNSPSC Code:
12352005
PubChem Substance ID:
329772508
NACRES:
NA.22

form

solid

reaction suitability

reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

mp

143-147 °C

SMILES string

CC1=C2C(OC(C)CC2)=NC3=C1C=CC=C3

InChI

1S/C14H15NO/c1-9-7-8-12-10(2)11-5-3-4-6-13(11)15-14(12)16-9/h3-6,9H,7-8H2,1-2H3

InChI key

ZENOEMLZOZWVRD-UHFFFAOYSA-N

Application

Ligand can be used in the presence of Pd(TFA)2 (Aldrich 299685) to promote C-H activation of β-Aryl-α-amino acids. This product has shown to be optimal with a 2:1 ratio of Ligand:Pd Source for several examples reported by the Yu group.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

ALD00002-VAR:
ALD00002-1G:
ALD00002-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCC7653
MKBR8065V

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