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923443

Sigma-Aldrich

PhMPhos

Synonym(s):

1-Diadamantylphosphino-1′-diphenylphosphinoferrocene

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About This Item

Empirical Formula (Hill Notation):
C42H48FeP2
Molecular Weight:
670.62
UNSPSC Code:
12352200
NACRES:
NA.21

form

powder

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

functional group

phosphine

Application

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

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Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

923443-VAR:
923443-500MG:
923443-100MG:
923443-BULK:

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