Skip to Content
Merck
All Photos(1)

Documents

Safety Information

920371

Sigma-Aldrich

Lithium hexafluorophosphate

99.9% trace metals basis

Synonym(s):

LBG 45864, Lithium fluophosphate, Lithium phosphorus fluoride

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
LiPF6
CAS Number:
21324-40-3
Molecular Weight:
151.91
MDL number:
MFCD00011096
UNSPSC Code:
12352302

Quality Level

200

Assay

99.9% trace metals basis

mp

200 °C (dec.) (lit.)

SMILES string

[Li+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Lithium hexafluorophosphate is a salt utilized as an electrolyte in lithium ion batteries. Recent advancements in the development of both additive scavengers (high selectivity & affinity toward unwanted species) and additive promoters (of LiPF6 dissociation) have greatly addressed electrolyte instability that commonly results in LiPF6 electrolyte containing battery performance degradation and lifetime shortening.

Signal Word

Danger

Hazard Statements

H301 - H314 - H372

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

Storage Class Code

6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Jung-Gu Han et al.
Advanced materials (Deerfield Beach, Fla.), 31(20), e1804822-e1804822 (2018-11-13)
In conjunction with electrolyte additives used for tuning the interfacial structures of electrodes, functional materials that eliminate or deactivate reactive substances generated by the degradation of LiPF6 -containing electrolytes in lithium-ion batteries offer a wide range of electrolyte formulation opportunities.
Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte
Liu J, et al.
Transactions of Nonferrous Metals Society of China, 20(2), 344-348 (2010)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service