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911534

Sigma-Aldrich

(4,4′-dMeObpy)NiCl2

Synonym(s):

4,4′-dimethoxy-2,2′-bipyridine nickel (II) chloride

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About This Item

Empirical Formula (Hill Notation):
C12H12Cl2N2NiO2
CAS Number:
1303613-81-1
Molecular Weight:
345.84
UNSPSC Code:
12161600
NACRES:
NA.23

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Application

(4,4′-dMeObpy)NiCl2 is a Ni catalyst used for a variety of cross-coupling reactions.

Other Notes

Photocatalytic α-Acylation of Ethers

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - Repr. 2 - STOT RE 1 Inhalation

Target Organs

Respiratory Tract

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

911534-BULK:
911534-250MG:
911534-1G:
911534-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ5486

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Zhongdong Sun et al.
Organic letters, 19(14), 3727-3730 (2017-07-12)
Direct coupling of ethers and acyl halides was promoted by a binary catalytic system comprising an Ir-based photocatalyst and a Ni complex under blue-light irradiation. Photocatalysts with high triplet energy directed the catalysis, and the reaction likely proceeded by triplet-triplet

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