Skip to Content
Merck
All Photos(2)

Key Documents

View All Documentation

Safety Information

731382

Sigma-Aldrich

(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

greener alternative

Synonym(s):

Fe(R,R-PDP), Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, White-Chen catalyst, [Fe(R,R-PDP)(CH3CN)2](SbF6)2

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C24H32F12FeN6Sb2
CAS Number:
1361315-26-5
Molecular Weight:
931.90
MDL number:
MFCD16038114
UNSPSC Code:
12161600
PubChem Substance ID:
329764650
NACRES:
NA.22

form

powder

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

215-226 °C

greener alternative category

, Aligned

SMILES string

[Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4

InChI

1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1

InChI key

XUNWHBGEOCZDBX-QSKJABRXSA-B

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

731382-500MG:4548173305745
731382-100MG:4548173305738
731382-VAR:
731382-BULK:

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
38696MMV
38696MM

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service