709859
TEMPO on silica gel
Synonym(s):
2,2,6,6-Tetramethyl-1-piperinyloxy, free radical on silica gel, SiliaCAT® TEMPO
About This Item
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form
solid
storage temp.
2-8°C
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General description
Application
Legal Information
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Listings
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JAN Code
709859-5G:
709859-25G:
709859-BULK:
709859-VAR:
Certificates of Analysis (COA)
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Articles
TEMPO (2,2,6,6-Tetramethylpiperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl) and its derivatives are stable nitroxy radicals used as catalysts in organic oxidation reactions. TEMPO was discovered by Lebedev and Kazarnovskii in 1960. The stable free radical nature of TEMPO is due to the presence of bulky substituent groups, which hinder the reaction of the free radical with other molecules.
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