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Safety Information

701742

Sigma-Aldrich

Copper(I) chloride - bis(lithium chloride) complex

1 M in THF

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About This Item

Linear Formula:
CuCl · 2LiCl
Molecular Weight:
183.79
UNSPSC Code:
12161600
PubChem Substance ID:
329762317
NACRES:
NA.22

form

liquid

reaction suitability

core: copper
reagent type: catalyst

concentration

1 M in THF

refractive index

n20/D 1.442

density

1.015 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.Cl[Cu]

InChI

1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3

InChI key

QJRAZNXUNZEAQH-UHFFFAOYSA-K

Application

Solution used in Cu(I) transmetallation for amination reaction

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

62.6 °F

Flash Point(C)

17.0 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

701742-BULK:
701742-50ML:4548173299518
701742-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL2905
SHBJ8231
SHBG2790V
SHBC3552
07928EJ

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Kienle, M. et al.
Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Vicente Del Amo et al.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)

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