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687952

Sigma-Aldrich

(Cyclohexylmethyl)magnesium bromide solution

Synonym(s):

Cyclohexylmethylmagnesium bromide

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About This Item

Empirical Formula (Hill Notation):
C7H13BrMg
CAS Number:
35166-78-0
Molecular Weight:
201.39
MDL number:
MFCD02260210
UNSPSC Code:
12352103
PubChem Substance ID:
329760828
NACRES:
NA.22

Quality Level

100

form

liquid

reaction suitability

reaction type: Grignard Reaction

density

0.966 g/mL at 25 °C

SMILES string

Br[Mg]CC1CCCCC1

InChI

1S/C7H13.BrH.Mg/c1-7-5-3-2-4-6-7;;/h7H,1-6H2;1H;/q;;+1/p-1

InChI key

ZBCIOGFGZRNNEC-UHFFFAOYSA-M

Application

Reactant involved in:
  • Isomerization polymerization of alkenylcyclohexanes
  • Intramolecular rearrangements of vinylidenecyclopropanes
  • Cycloisomerization of cyclic and acyclic enynes

Additionally reactant involved in synthesis of biologically active molecules including:
  • Dipeptidyl boronic acid proteasome inhibitors
  • Substituted 1,3-dihydroindole-2-ones with antitumor effects
  • Sulfur-free transition state nucleoside analog inhibitors of methylthioadenosine nucleosidase and phosphorylase

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H351

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

687952-BULK:
687952-50ML:4548173290621
687952-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBF9773V
SHBB3302
55196KM
40496LK
22296DK

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