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Safety Information

685437

Sigma-Aldrich

(12-Phosphonododecyl)phosphonic acid

97%

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About This Item

Empirical Formula (Hill Notation):
C12H28O6P2
CAS Number:
Molecular Weight:
330.29
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

97%

form

solid

mp

181-187 °C

SMILES string

OP(O)(=O)CCCCCCCCCCCCP(O)(O)=O

InChI

1S/C12H28O6P2/c13-19(14,15)11-9-7-5-3-1-2-4-6-8-10-12-20(16,17)18/h1-12H2,(H2,13,14,15)(H2,16,17,18)

InChI key

BEPFDRNIALBIKQ-UHFFFAOYSA-N

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General description

(12-Phosphonododecyl)phosphonic acid (PDDPA) is a phosphonic acid derivate that forms a self-assembled monolayer (SAM) on a variety of nanoparticle surfaces. The phosphonate groups interact with the hydroxyl groups of the nanoparticles to form stable interfacial linkages.

Application

PDDPA can be used to functionalize zinc nanoparticles which may be used to modify the work function for solar cell (SC) based applications. It can also modify the surface of titanium by fabricating biomimetic calcium-phosphate layers which can be used in the surface treatment of dental implants.
SAMs on metal oxide surfaces. Preparation of organophosphonate multilayers on silicon and gold surfaces.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

685437-BULK:
685437-1G:
685437-VAR:


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Investigation of phosphonic acid surface modifications on zinc oxide nanoparticles under ambient conditions.
Qui?ones R, et al.
Thin Solid Films, 565(18), 155-164 (2014)
Journal of the American Chemical Society, 295-301 (1994)
Study of polymorphism using patterned self-assembled monolayers approach on metal substrates.
Qui?ones R, et al.
Applied Surface Science, 427(18), 97-105 (2018)
Structure and order of phosphonic acid-based self-assembled monolayers on Si (100).
Dubey M, et al.
Langmuir, 26(18), 14747-14754 (2010)
The Journal of Physical Chemistry, 2597-2601 (1988)

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Self-assembled monolayers (SAMs) have attracted enormous interest for a wide variety of applications in micro- and nano-technology. In this article, we compare the benefits of three different classes of SAM systems (alkylthiolates on gold.

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