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Safety Information

683159

Sigma-Aldrich

Chiralyst P468

Umicore

Synonym(s):

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, Bis(1,5-cyclooctadiene)rhodium triflate

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About This Item

Empirical Formula (Hill Notation):
C17H24F3O3RhS
CAS Number:
99326-34-8
Molecular Weight:
468.34
MDL number:
MFCD00143752
UNSPSC Code:
12161600
PubChem Substance ID:
329760799
NACRES:
NA.22

Quality Level

100

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

mp

159 °C (dec. literature value) (lit.)
83-97 °C (dec. experimental value)

SMILES string

[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b2*2-1-,8-7-;;

InChI key

GOPBTCMAUMSOBX-QMDOQEJBSA-M

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Related Categories

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

683159-500MG:4548173923437
683159-VAR:
683159-2G:4548173923420
683159-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN3592
MKCK4740
MKCD6826
MKCC3323
MKBX5329V

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Articles

Umicore Precatalysts

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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