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Safety Information

682071

Sigma-Aldrich

2-(Hydroxymethyl)phenylboronic acid cyclic monoester

97%

Synonym(s):

1,3-Dihydro-1-hydroxy-2,1-benzoxaborole, 2-(Hydroxymethyl)phenylboronic acid hemiester

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About This Item

Empirical Formula (Hill Notation):
C7H7BO2
CAS Number:
5735-41-1
Molecular Weight:
133.94
MDL number:
MFCD01075677
UNSPSC Code:
12352103
PubChem Substance ID:
329760770
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

95-100 °C

SMILES string

OB1OCc2ccccc12

InChI

1S/C7H7BO2/c9-8-7-4-2-1-3-6(7)5-10-8/h1-4,9H,5H2

InChI key

XOQABDOICLHPIS-UHFFFAOYSA-N

Related Categories

Application

Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

682071-VAR:
682071-BULK:
682071-1G:
682071-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCD2249
MKBV9458V
MKBS5857V
MKBN8765V
MKBG6125V

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Eric C Hansen et al.
Journal of the American Chemical Society, 128(25), 8142-8143 (2006-06-22)
A novel mode of regiochemical control over the allylic [1,3]-transposition of silyloxy groups catalyzed by Re2O7 has been developed. This strategy relies on a cis-oriented vinyl boronate, generated from the Alder-ene reaction of homoallylic silyl ethers and alkynyl boronates, to
Synthesis, 1148-1148 (2006)

Global Trade Item Number

SKUGTIN
682071-1G4061826066782
682071-5G4061832881065

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