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Safety Information

678015

Sigma-Aldrich

4,7-Dichloro-1,10-phenanthroline

97%

Synonym(s):

4,7-Dichloro-o-phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C12H6Cl2N2
CAS Number:
5394-23-0
Molecular Weight:
249.10
MDL number:
MFCD00233882
UNSPSC Code:
12352300
PubChem Substance ID:
24885412
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

243-247 °C

SMILES string

Clc1ccnc2c1ccc3c(Cl)ccnc23

InChI

1S/C12H6Cl2N2/c13-9-3-5-15-11-7(9)1-2-8-10(14)4-6-16-12(8)11/h1-6H

InChI key

GIEQBYJCGYHHSU-UHFFFAOYSA-N

Related Categories

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301,H315,H318,H335

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

678015-VAR:
678015-BULK:
678015-1G:
678015-250MG:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN1627
MKCB6564
MKBK3020V
MKBD4051
59098PJ

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Ryan A Altman et al.
Organic letters, 8(13), 2779-2782 (2006-06-16)
[reaction: see text] 4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazole with aryl iodides and bromides under mild conditions. A variety of hindered and functionalized imidazoles and aryl halides were transformed in good
Anna M Maroń et al.
Dalton transactions (Cambridge, England : 2003), 49(14), 4441-4453 (2020-03-18)
Three Re(i) carbonyl complexes [ReCl(CO)3(Ln)] bearing 2,2'-bipyridine, 2,2':6',2''-terpyridine, and 1,10-phenanthroline functionalized with diphenylamine/or triphenylamine units (L1-L3) were synthesized to explore the impact of highly electron donating units appended to the imine ligand on the thermal and optoelectronic properties of Re(i)

Global Trade Item Number

SKUGTIN
678015-250MG4061833549766
678015-1G4061826700235

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