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567205

Sigma-Aldrich

Tetramethylthiuram monosulfide

97%

Synonym(s):

UNADS

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About This Item

Linear Formula:
((H3C)2NCS)2S
CAS Number:
97-74-5
Molecular Weight:
208.37
EC Number:
202-605-7
MDL number:
MFCD00014870
UNSPSC Code:
12352100
PubChem Substance ID:
24880353
NACRES:
NA.22

Quality Level

100

Assay

97%

mp

107-111 °C (lit.)

functional group

amine
dithiocarbamate
thioether

SMILES string

CN(C)C(=S)SC(=S)N(C)C

InChI

1S/C6H12N2S3/c1-7(2)5(9)11-6(10)8(3)4/h1-4H3

InChI key

REQPQFUJGGOFQL-UHFFFAOYSA-N

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Related Categories

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H317,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

312.8 °F - closed cup

Flash Point(C)

156 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

567205-25G:
567205-100G:
567205-BULK:
567205-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCB6183
SHBC3940V
SHBB3576V
18496BP
43996CK

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E Schreiner et al.
Toxicology letters, 25(2), 147-152 (1985-05-01)
The epoxide hydrolase (EH) activity in the liver of adult female Wistar rats significantly increased 18 h after the administration by gavage of tetramethyl thiuramdisulfide (TMTD, 1 mmol/kg) or tetramethyl thiurammonosulfide (TMTM, 2 mmol/kg). No increase was observed 5 h
Allergic contact dermatitis of the eyelids from rubber chemicals.
J C Cabrita et al.
Contact dermatitis, 24(2), 145-146 (1991-02-01)
Toxicity studies on tetramethylthiuram monosulfide.
O T Alanis et al.
Environmental research, 28(1), 199-211 (1982-06-01)
A Rannug et al.
Chemico-biological interactions, 49(3), 329-340 (1984-05-01)
In recent years data have accumulated regarding genotoxic properties of dithiocarbamic acid derivatives. The results from the present work indicate that the mutagenicity of these compounds depends on an indirect effect via oxygen radicals. Mutagenicity of tetramethylthiuram disulfide ( TMTD
Contact allergy to Nobecutan.
B Pock-Steen
Contact dermatitis, 18(1), 52-53 (1988-01-01)
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