561673
1-Naphthylmagnesium bromide solution
0.25 M slurry in THF
About This Item
Recommended Products
reaction suitability
reaction type: Grignard Reaction
concentration
0.25 M slurry in THF
bp
65 °C
density
0.908 g/mL at 25 °C
SMILES string
Br[Mg]c1cccc2ccccc12
InChI
1S/C10H7.BrH.Mg/c1-2-6-10-8-4-3-7-9(10)5-1;;/h1-7H;1H;/q;;+1/p-1
InChI key
PZIIGUMPOSVMSD-UHFFFAOYSA-M
Application
- To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions.
- As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.
Legal Information
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
PRTR
Class I Designated Chemical Substances
FSL
Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
561673-VAR:
561673-BULK:
561673-50ML:4548173170060
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