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514381

Sigma-Aldrich

Titanium(III) chloride

≥99.995% trace metals basis

Synonym(s):

Titanium trichloride

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About This Item

Linear Formula:
TiCl3
CAS Number:
7705-07-9
Molecular Weight:
154.23
EC Number:
231-728-9
MDL number:
MFCD00011266
UNSPSC Code:
26111700
PubChem Substance ID:
24873756

Assay

≥99.995% trace metals basis

form

crystalline

reaction suitability

reagent type: catalyst
core: titanium

mp

440 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

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Application

Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H250,H314

Hazard Classifications

Pyr. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

514381-BULK:
514381-1G:4548173164786
514381-VAR:
514381-1G-PW:
514381-5G:4548173164793
514381-5G-PW:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN3844V
MKBN2967V
MKBJ4298V
MKBJ9739V
MKBG3063V

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Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating
Investigation into the effectiveness of surface treatment on poly(methyl methacrylate) when exposed in the mouth.
M D Murray
The Journal of prosthetic dentistry, 59(3), 368-373 (1988-03-01)
D J Kushner et al.
Analytical biochemistry, 133(1), 116-119 (1983-08-01)
Hydroxamic acid siderophores were observed to be inactivated by exposure to titanium(III) chloride. To study the reaction, a series of eight model hydroxamic acids were prepared and reacted with titanium(III) chloride. The products were shown by ir and NMR comparisons
Yan Zhang et al.
Organic & biomolecular chemistry, 9(13), 4977-4982 (2011-05-21)
N-N bond cleavage in hydrazines is widely used in the preparation of amines and thus occupies a significant place in organic synthesis. In this paper, we report a new method for the reductive cleavage of N-N bonds in hydrazines by
C P Offen et al.
Xenobiotica; the fate of foreign compounds in biological systems, 15(6), 503-511 (1985-06-01)
The metabolic fate of chlormethiazole in healthy male subjects has been investigated following the oral administration of a single dose of chlormethiazole edisylate. Five urinary C-oxidation metabolites were identified and shown to be identical with previously reported metabolites. A novel
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