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Safety Information

495956

Sigma-Aldrich

trans-3-(tert-Butyldimethylsilyloxy)-N,N-dimethyl-1,3-butadien-1-amine

90%

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About This Item

Linear Formula:
(CH3)3CSi(CH3)2OC(=CH2)CH=CHN(CH3)2
CAS Number:
194233-66-4
Molecular Weight:
227.42
MDL number:
MFCD01863582
UNSPSC Code:
12352100
PubChem Substance ID:
24873004
NACRES:
NA.22

Quality Level

100

Assay

90%

refractive index

n20/D 1.493 (lit.)

bp

234 °C (lit.)

density

0.878 g/mL at 25 °C (lit.)

functional group

amine

storage temp.

2-8°C

SMILES string

[H]\C(=C(\[H])C(=C)O[Si](C)(C)C(C)(C)C)N(C)C

InChI

1S/C12H25NOSi/c1-11(9-10-13(5)6)14-15(7,8)12(2,3)4/h9-10H,1H2,2-8H3/b10-9+

InChI key

NSCKABIMFIKUEF-MDZDMXLPSA-N

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

199.4 °F - closed cup

Flash Point(C)

93 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

495956-BULK:
495956-VAR:
495956-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCH8438
MKCG2177
MKCF9475
MKBX2635V
MKBS2118V

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Preparation and Diels-Alder Reactivity of 1-Amino-3-siloxy-1,3-butadienes.
Kozmin SA and Rawal VH.
The Journal of Organic Chemistry, 62(16), 5252-5253 (1997)

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