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435716

Sigma-Aldrich

3-(Trihydroxysilyl)propyl methylphosphonate, monosodium salt solution

50 wt. % in H2O

Synonym(s):

Sodium 3-trihydroxysilylpropyl methylphosphonate

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About This Item

Linear Formula:
CH3P(O)(ONa)O(CH2)3Si(OH)3
CAS Number:
84962-98-1
Molecular Weight:
238.18
EC Number:
284-799-3
MDL number:
MFCD00274617
UNSPSC Code:
12352100
PubChem Substance ID:
24867253
NACRES:
NA.22

form

liquid

concentration

50 wt. % in H2O

impurities

4 wt. % methyl alcohol
4 wt. % other silane-based salts
5 wt. % sodium methyl methylphosphonate

density

1.252 g/mL at 25 °C

SMILES string

[Na+].CP([O-])(=O)OCCC[Si](O)(O)O

InChI

1S/C4H13O6PSi.Na/c1-11(5,6)10-3-2-4-12(7,8)9;/h7-9H,2-4H2,1H3,(H,5,6);/q;+1/p-1

InChI key

MKAWPVONNWUREJ-UHFFFAOYSA-M

Application

3-(Trihydroxysilyl)propyl methylphosphonate, monosodium salt was used for the following syntheses:
  • near-infrared dye-doped nanoparticles (NPs)
  • as single silica source for the fabrication of phosphonate-rich organosilica layered hybrid material (PSLM)
  • Gd/SiO2 nanoparticles
  • mesoporous silica nanoparticles
  • CdSe/ZnS/silica functionalized nanocrystals

Pictograms

Health hazard
GHS08

Signal Word

Warning

Hazard Statements

H371

Hazard Classifications

STOT SE 2

Target Organs

Eyes,Central nervous system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

174.2 °F

Flash Point(C)

79 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

435716-100ML:4548173911373
435716-VAR:
435716-BULK:
435716-500ML:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chris Daikopoulos et al.
Journal of hazardous materials, 270, 118-126 (2014-02-26)
A phosphonate-rich organosilica layered hybrid material (PSLM) made of 3-(trihydroxysilyl)propyl methylphosphonate, monosodium salt, as the single silica source, has been obtained from its aqueous solution through a xerogel process and mild thermal aging. The method is simple, affording bulk quantities
Mesoporous silica nanoparticles facilitate delivery of siRNA to shutdown signaling pathways in mammalian cells.
Christopher Hom et al.
Small (Weinheim an der Bergstrasse, Germany), 6(11), 1185-1190 (2010-05-13)
Robert I Nooney et al.
Analytical and bioanalytical chemistry, 393(4), 1143-1149 (2008-10-11)
There is substantial interest in the development of near-infrared dye-doped nanoparticles (NPs) for a range of applications including immunocytochemistry, immunosorbent assays, flow cytometry, and DNA/protein microarray analysis. The main motivation for this work is the significant increase in NP fluorescence
Preparation and properties of various magnetic nanoparticles.
Drbohlavova J, et al.
Sensors, 9(4), 2352-2362 (2009)
Sławomir Oszwałdowski et al.
Analytical and bioanalytical chemistry, 399(8), 2831-2842 (2011-01-27)
In the present work, CdSe nanocrystals (NCs) synthesized with a trioctylphosphine surface passivation layer were modified using amphiphilic molecules to form a surface bilayer capable of providing stable NCs aqueous solutions. Such modified nanocrystals were used as a test solute

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