409405
Chlorotris(trimethylsilyl)silane
97%
Synonym(s):
1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride
About This Item
Recommended Products
Quality Level
Assay
97%
form
solid
mp
50-52 °C (lit.)
SMILES string
C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
InChI key
HCOROOJWVHFMRJ-UHFFFAOYSA-N
General description
Application
Used for:
- Insertion into a P-P bond
- Diastereoselective aldol and cascade reactions
- Preparation of hypersilyl substituted monophosphines and diphosphines
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
87.8 °F - closed cup
Flash Point(C)
31 °C - closed cup
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
FSL
Group 2: Flammable solids
Flammable solid
Hazardous rank III
JAN Code
409405-BULK:
409405-25G:
409405-VAR:
409405-10G:
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The super silyl group is a powerful tool for the synthetic chemist, showing great efficacy in various carbon–carbon bond forming reactions.
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