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Safety Information

386456

Sigma-Aldrich

Diethylamine

purified by redistillation, 99.5%

Synonym(s):

N-ethyl-ethanamine, DEA, Diethamine, Diethyl amine

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About This Item

Linear Formula:
(C2H5)2NH
CAS Number:
109-89-7
Molecular Weight:
73.14
Beilstein:
605268
EC Number:
203-716-3
MDL number:
MFCD00009032
UNSPSC Code:
12191502
PubChem Substance ID:
24864093
NACRES:
NA.22
Assay:
99.5%
technique(s):
ELISA: suitable
bp:
55 °C (lit.)
vapor pressure:
14.14 psi ( 55 °C)
180 mmHg ( 20 °C)
3.51 psi ( 20 °C)

vapor density

2.5 (vs air)

Quality Level

200

vapor pressure

14.14 psi ( 55 °C)
180 mmHg ( 20 °C)
3.51 psi ( 20 °C)

Assay

99.5%

form

liquid

autoignition temp.

594 °F

purified by

redistillation

expl. lim.

10.1 %

technique(s)

ELISA: suitable

refractive index

n20/D 1.385 (lit.)

pH

13 (20 °C, 100 g/L)

bp

55 °C (lit.)

mp

−50 °C (lit.)

density

0.707 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CCNCC

InChI

1S/C4H11N/c1-3-5-4-2/h5H,3-4H2,1-2H3

InChI key

HPNMFZURTQLUMO-UHFFFAOYSA-N

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Application

Diethylamine can be used as a better template for the crystallization of the silicoaluminophosphate molecular sieves (SAPO-34) with high purity and crystallinity as compared to other templates. It can react with furfural and cyanoacetic ester to form bicyclo[3.2.1]octanes. It can also be used as an amino functionalized monomer which can interact with chitosan to synthesize hydrogel with potential applications in drug delivery systems.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

-14.8 °F - closed cup

Flash Point(C)

-26 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

386456-VAR:
386456-BULK:
386456-1L:4548173939339
386456-100ML:4548173939322

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL2126
SHBL2018
SHBH0334V
SHBD9029V
SHBC5129V

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Synthesis of SAPO-34 templated by diethylamine: Crystallization process and Si distribution in the crystals
Liu G, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 114(1-3), 416-423 (2008)
A New Synthetic Approach to Functionalized Bicyclo [3.2.1] octanes
Ismiev A, et al.
Russ. J. Gen. Chem., 88(7), 1533-1536 (2018)
A simple strategy for robust preparation and characterisation of hydrogels derived from chitosan and amino functional monomers for biomedical applications
Khan F, et al.
Journal of Material Chemistry B: Materials for Biology and Medicine, 6(31), 5115-5129 (2018)
Katina S S Dossou et al.
Journal of chromatography. A, 1216(44), 7450-7455 (2009-06-26)
A polysaccharide-based chiral stationary phase (Sepapak-4), with cellulose tris(4-chloro-3-methylphenylcarbamate) as chiral selector, has been investigated in liquid chromatography (LC). Its enantioresolution power was evaluated towards 13 basic amino-drugs with widely different structures and polarities, using polar organic mobile phases. After
Roberto Cirilli et al.
Analytical chemistry, 81(9), 3560-3570 (2009-03-28)
Second-order rate constants of the diethylamine-promoted enantiomerization of 2-[2-(1-methyl-1H-pyrrol-2-yl)-2-oxo-1-phenylethyl]-isoindole-1,3-dione, a chiral alpha-substituted ketone endowed with high anti-MAO activity type-A, were measured by dynamic high-performance liquid chromatography (DHPLC), stopped-flow high-performance liquid chromatography (sf-HPLC), and a classical method based on enantioselective HPLC
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