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375187

Sigma-Aldrich

Trimethyltin chloride solution

1.0 M in hexanes

Synonym(s):

Chlorotrimethylstannane, Chlorotrimethyltin, Trimethylchlorostannane, Trimethylchlorotin, Trimethylstannyl chloride, Trimethyltin chloride

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About This Item

Linear Formula:
(CH3)3SnCl
CAS Number:
1066-45-1
Molecular Weight:
199.27
Beilstein:
3535111
MDL number:
MFCD00000520
UNSPSC Code:
12352103
PubChem Substance ID:
24863370
NACRES:
NA.22

form

liquid

concentration

1.0 M in hexanes

density

0.797 g/mL at 25 °C

SMILES string

C[Sn](C)(C)Cl

InChI

1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1

InChI key

KWTSZCJMWHGPOS-UHFFFAOYSA-M

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Application

Trimethyltin chloride solution (1.0 M in hexanes) can be used as a reagent in the synthesis of conjugated polymers based on isoindigo as acceptor and syn- or anti-benzo[1,2-b:5,4-b′]difuran (BDF) as a donor by Stille cross-coupling reaction. It can further be used for the investigation of optical, electrochemical and photovoltaic properties.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Central nervous system, Nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-9.4 °F - closed cup

Flash Point(C)

-23 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

375187-25ML:4548173141251
375187-BULK:
375187-100ML:4548173141244
375187-VAR:
375187-4X25ML:4548173336565

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP9053
MKCN7621
SHBJ8521
SHBH1159V
SHBG2797V

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Synthesis and photovoltaic properties of new conjugated polymers based on syn-and anti-benzodifuran
Hu C, et al.
Polym. Chem., 3(10), 2949-2955 (2012)
Nguyen Quynh Huong et al.
Biological & pharmaceutical bulletin, 34(12), 1856-1863 (2011-12-02)
The organotin trimethyltin (TMT) is well known to cause neuronal degeneration in the hippocampal dentate gyrus of mice. The first purpose of the present study was to examine whether the cyclooxygenase (COX) inhibitor indomethacin could ameliorate neuronal degeneration in the
Ana-Maria Florea et al.
Cell calcium, 37(3), 251-258 (2005-01-27)
Humans are exposed to organotins, like trimethyltin (TMT) chloride via air, water and food, and intoxication might result in severe health complications. Toxic effects of organotin compounds are well documented, but possible mechanisms remain unclear and only little information is
Koichi Kawada et al.
Journal of neuroscience research, 86(7), 1635-1646 (2008-01-10)
Our earlier study demonstrated that in vivo acute treatment with trimethyltin chloride (TMT) produces severe neuronal damage in the dentate gyrus and cognition impairment in mice. In the present study, we assessed whether TMT was capable of causing neuronal degeneration
Guangshu Zhai et al.
Chemosphere, 72(3), 389-399 (2008-04-25)
The photodegradation of methyltins, as environmental pollutants, has scarcely been studied so far because of the shortage of rapid and sensitive speciation methods, even though they have very simple structures. The photodegradation of monomethyltin trichloride (MMT), dimethyltin dichloride (DMT) and
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