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343803

Sigma-Aldrich

Methanol-d4

≥99.8 atom % D, contains 0.03 % (v/v) TMS

Synonym(s):

Methyl-d3 alcohol d, Tetradeuteromethanol

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About This Item

Linear Formula:
CD3OD
CAS Number:
811-98-3
Molecular Weight:
36.07
Beilstein:
1733278
EC Number:
212-378-6
MDL number:
MFCD00044637
UNSPSC Code:
12352104
PubChem Substance ID:
24861205
NACRES:
NA.21

isotopic purity

≥99.8 atom % D

Quality Level

200

Assay

≥99% (CP)

form

liquid

contains

0.03 % (v/v) TMS

expl. lim.

5.5-36.5 % (lit.)

technique(s)

NMR: suitable

impurities

≤0.025% water
water

refractive index

n20/D 1.326 (lit.)

bp

65.4 °C (lit.)

mp

-99 °C (lit.)

density

0.888 g/mL at 25 °C (lit.)

format

mixture

SMILES string

[2H]OC([2H])([2H])[2H]

InChI

1S/CH4O/c1-2/h2H,1H3/i1D3,2D

InChI key

OKKJLVBELUTLKV-MZCSYVLQSA-N

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General description

Methanol-d4 is a deuterated NMR solvent containing 0.03 % (v/v) TMS (trimethylsilane). It is useful in NMR-based research and analyses.

Application

Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

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accessory

Product No.
Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes,Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

49.5 °F - closed cup

Flash Point(C)

9.7 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Alcohols
Hazardous rank II

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

343803-5G:4548173138053
343803-BULK:
343803-50G:4548173138046
343803-VAR:
343803-10X1ML:4548174009604
343803-10G:4548173138022
343803-10X0.75ML:4548174005651
343803-1G:4548173138039

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Certificates of Analysis (COA)

Lot/Batch Number
MBBD3158
MBBD1615
MBBD1385
MBBD0938
MBBD0108

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Far-Infrared and Raman Spectra of Solid Methanol and Methanol-d4.
Durig JR, et al.
J. Chem. Phys., 54(11), 4863-4870 (1971)
Antithrombotic Phenolics from the Stems of Parthenocissus tricuspidata Possess Anti-inflammatory Effect.
Nguyen PH, et al.
Bull. Korean Chem. Soc., 35(6), 1763-1763 (2014)
The Rates of Methoxyl Exchange of Camphor and Norcamphor Dimethyl Ketals in Methanol-d4.
Traylor TG and Perrin CL.
Journal of the American Chemical Society, 88(21), 4934-4942 (1966)
Cheng-Kun Lin et al.
Organic & biomolecular chemistry, 13(7), 2100-2107 (2014-12-20)
A straightforward synthesis of novel, 2-heterocyclyl polyhydroxylated pyrrolidines is described. Stereocontrolled additions of nucleophiles to cyclic nitrones generated the corresponding 2,3-trans adducts, allowing the synthesis of the corresponding pyrrolidines via key intermediates bearing an alkyne and a nitrile oxide. Three
Jon Kapla et al.
Physical chemistry chemical physics : PCCP, 17(34), 22438-22447 (2015-08-08)
The disaccharide trehalose (TRH) strongly affects the physical properties of lipid bilayers. We investigate interactions between lipid membranes formed by 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and TRH using NMR spectroscopy and molecular dynamics (MD) computer simulations. We compare dipolar couplings derived from DMPC/TRH
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