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334987

Sigma-Aldrich

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate hydrate

97%

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About This Item

Empirical Formula (Hill Notation):
C16H24BF4Rh · xH2O
CAS Number:
207124-65-0
Molecular Weight:
406.07 (anhydrous basis)
MDL number:
MFCD00167214
UNSPSC Code:
12161600
PubChem Substance ID:
24860274
NACRES:
NA.22

Assay

97%

reaction suitability

core: rhodium
reagent type: catalyst

mp

165 °C (dec.) (lit.)

SMILES string

O.[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.H2O.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;;/h2*1-2,7-8H,3-6H2;;1H2;/q;;-1;;+1/b2*2-1-,8-7-;;;

InChI key

NYMNQNLSUITCLM-DIURZKMRSA-N

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Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H228,H315,H317,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

334987-500MG:4548173136561
334987-100MG:4548173136554
334987-BULK:
334987-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBJ9590V
MKBD6317V
MKBD6317
08313BE
03805PA

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Articles

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Vinyl-metal reagents play a pivotal role in organic synthesis. Among the vinyl-metal reagents available, silicon-based reagents are of increasing importance. This is largely due to their low cost, minimal toxicity, ease of handling, and the simplicity of byproduct removal.

Hydrosilylation Catalyst

A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.

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