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333972

Sigma-Aldrich

Zirconium(IV) propoxide solution

70 wt. % in 1-propanol

Synonym(s):

Tetrapropyl zirconate

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About This Item

Linear Formula:
Zr(OCH2CH2CH3)4
CAS Number:
Molecular Weight:
327.57
Beilstein:
3679533
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

form

solution

Quality Level

composition

Zr, 18.1-22.3% gravimetric

reaction suitability

core: zirconium
reagent type: catalyst

concentration

70 wt. % in 1-propanol

refractive index

n20/D 1.451

bp

208 °C/0.1 mmHg

density

1.044 g/mL at 25 °C

SMILES string

CCCO[Zr](OCCC)(OCCC)OCCC

InChI

1S/4C3H7O.Zr/c4*1-2-3-4;/h4*2-3H2,1H3;/q4*-1;+4

InChI key

XPGAWFIWCWKDDL-UHFFFAOYSA-N

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Application

Zirconium(IV) propoxide solution is a metal alkoxide solution that is highly reactive with water. It can be used as a precursor material for the synthesis of zirconium oxide thin films by atmospheric pressure electrospray. Zirconium(IV) propoxide can also be used in the preparation of stable sols for potential usage in optical, electronic and magnetic applications.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

82.9 °F - closed cup

Flash Point(C)

28.3 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

333972-500ML:4548173954950
333972-5ML:
333972-VAR:
333972-BULK:
333972-100ML:4548173954943
333972-5L:


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Heine, M.C.; et al.
Combustion and Flame, 144 (4), 809-820 (2006)
Sol-gel templating of membranes to form thick, porous titania, titania/zirconia and titania/silica films
Schattka JH, et al.
Journal of Materials Chemistry, 16(15), 1414-1420 (2006)
Ruohong Sui et al.
Langmuir : the ACS journal of surfaces and colloids, 22(9), 4390-4396 (2006-04-19)
The objective of the present study was to synthesize porous ZrO2 aerogels with a nanostructure via a direct sol-gel route in the green solvent supercritical carbon dioxide (scCO2). The synthesis involved the coordination and polycondensation of a zirconium alkoxide using

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