330744
Tetrapropylammonium perruthenate
97%
Synonym(s):
TPAP
About This Item
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Quality Level
Assay
97%
form
solid
reaction suitability
reagent type: oxidant
mp
~160 °C (dec.) (lit.)
functional group
amine
SMILES string
[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
InChI
1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
InChI key
NQSIKKSFBQCBSI-UHFFFAOYSA-N
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General description
Application
- For the conversion of sulfides to sulfones by oxidation reaction.
- In the isomerization of allylic alcohols into the corresponding saturated carbonyl derivatives.
- Along with N-methylmorpholine N-oxide (NMO) for the cleavage of glycol to carboxylic acids.
TPAP can also be used as an oxidizing reagent:
- For the oxidation of benzyl alcohol to benzaldehyde and steroidal alcohols to corresponding ketones.
- To convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals.
- To oxidize hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
JAN Code
330744-50G:
330744-VAR:
330744-BULK:
330744-250MG:
330744-1G:
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