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327867

Sigma-Aldrich

4-Bromo-2,6-difluoroaniline

98%

Synonym(s):

(4-Bromo-2,6-difluorophenyl)amine, 2,6-Difluoro-4-bromoaniline, 4-Bromo-2,6-difluorobenzenamine

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About This Item

Linear Formula:
BrC6H2(F)2NH2
CAS Number:
67567-26-4
Molecular Weight:
208.00
MDL number:
MFCD00013389
UNSPSC Code:
12352100
PubChem Substance ID:
24859699
NACRES:
NA.22

Quality Level

200

Assay

98%

mp

63-65 °C (lit.)

functional group

bromo
fluoro

SMILES string

Nc1c(F)cc(Br)cc1F

InChI

1S/C6H4BrF2N/c7-3-1-4(8)6(10)5(9)2-3/h1-2H,10H2

InChI key

BFQSQUAVMNHOEF-UHFFFAOYSA-N

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Application

4-Bromo-2,6-difluoroaniline was used in synthesis of:
  • ammonium 5-bromo-7-fluorobenzo-2-oxa-1,3-diazole-4-sulphonate, fluorogenic derivatizating reagent for the determination of aminothiols by HPLC
  • olefin tolanes
  • 1-(4-amino-3,5-difluoro)-2-(4-butyloxyphenyl)ethyne
  • 4′′-n-butyloxy-3,5-difluoroterphenyl-4-amine
  • 4-(3-methylbut-1-yn-3-ol)-2,6-difluoroaniline

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

327867-BULK:
327867-1G:
327867-VAR:
327867-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
1404080V
1393577V
1404080
1393577
S46407

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Tailoring the physical properties of some high birefringence isothiocyanato-based liquid crystals.
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Liq. Cryst., 31(4), 541-555 (2004)
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Altered levels of aminothiols in biological fluids are thought to be an important risk indicator for several diseases, and reliable methods for the accurate determination of aminothiols concentrations in plasma are thus required. In this paper ammonium 5-bromo-7-fluorobenzo-2-oxa-1,3-diazole-4-sulphonate (SBD-BF) is

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