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325945

Sigma-Aldrich

Terbium(III) nitrate pentahydrate

99.9% trace metals basis

Synonym(s):

Terbium nitrate pentahydrate, Terbium(3+) nitrate pentahydrate

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About This Item

Linear Formula:
Tb(NO3)3 · 5H2O
CAS Number:
57584-27-7
Molecular Weight:
435.02
EC Number:
233-138-7
MDL number:
MFCD00149867
UNSPSC Code:
12352302
PubChem Substance ID:
24859547
NACRES:
NA.23

Assay

99.9% trace metals basis

form

solid

reaction suitability

reagent type: catalyst
core: terbium

impurities

≤1500.0 ppm Trace Rare Earth Analysis

SMILES string

O.O.O.O.O.[Tb+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.5H2O.Tb/c3*2-1(3)4;;;;;;/h;;;5*1H2;/q3*-1;;;;;;+3

InChI key

YWROXJNVUWBEPC-UHFFFAOYSA-N

General description

Terbium(III) nitrate pentahydrate can be used as a dopant/precursor to prepare luminescent phosphors for various applications such as optical ceramics, white light emitting diodes, and photodynamic therapy.

Application

Terbium(III) nitrate pentahydrate can be used as:
  • A precursor to prepare Ce-doped terbium aluminum garnets by the photo-induced method.
  • A dopant to synthesize emission-tunable luminescent hydroxyapatite probe for bioimaging.
  • A starting material to prepare metal-organic frameworks for green laser applications.

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Danger

Hazard Statements

H272,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 1: Oxidizing solids
Nitrates
Hazardous rank I
1st oxidizing solid

JAN Code

325945-BULK:
325945-VAR:
325945-5G:
325945-25G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Eulogio J Llorent-Martínez et al.
Analytical and bioanalytical chemistry, 410(2), 391-398 (2017-11-18)
We propose an alternative approach for the development of analytical methods based on terbium-sensitized luminescence (TSL). TSL is based on the complexation between Tb(III) ions and fluorescent organic compounds that have appropriate functional groups to complex with Tb(III). We report
I Perhaita et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 130, 188-197 (2017-10-06)
A series of novel apatite-based Ca
Reineke, T.M. et al.
Journal of the American Chemical Society, 121, 1651-1651 (1999)
Poonam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 152, 304-310 (2015-08-02)
The ternary terbium(III) complexes [Tb(HDAP)3⋅biq], [Tb(HDAP)3⋅dmph] and [Tb(HDAP)3⋅bathophen] were prepared by using methoxy substituted hydroxyketone ligand HDAP (2-hydroxy-4,6-dimethoxyacetophenone) and an ancillary ligand 2,2-biquinoline or 5,6-dimethyl-1,10-phenanthroline or bathophenanthroline respectively. The ligand and synthesized complexes were characterised based on elemental analysis, FT-IR

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