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308919

Sigma-Aldrich

2-Bromo-4-fluoroanisole

96%

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About This Item

Linear Formula:
BrC6H3(F)OCH3
CAS Number:
452-08-4
Molecular Weight:
205.02
MDL number:
MFCD00012014
UNSPSC Code:
12352100
PubChem Substance ID:
24858699
NACRES:
NA.22

Quality Level

100

Assay

96%

form

liquid

refractive index

n20/D 1.545 (lit.)

bp

89 °C/1 mmHg (lit.)

density

1.581 g/mL at 25 °C (lit.)

functional group

bromo
fluoro

SMILES string

COc1ccc(F)cc1Br

InChI

1S/C7H6BrFO/c1-10-7-3-2-5(9)4-6(7)8/h2-4H,1H3

InChI key

JIQXVIJARQLCOY-UHFFFAOYSA-N

Related Categories

Application

2-Bromo-4-fluoroanisole was used in the synthesis of (5-fluoro-2-methoxyphenyl)methanol.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

208.4 °F - closed cup

Flash Point(C)

98 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

308919-BULK:
308919-5G:
308919-25G:
308919-100G:
308919-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBZ2225V
MKBW2492V
MKBP7707V
MKBK5191V
MKBJ9789V

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Catherine N Slattery et al.
The Journal of organic chemistry, 78(12), 5955-5963 (2013-05-31)
An efficient synthetic approach leading to introduction of the hydroxymethyl group to an aryl moiety via combination of the Bouveault formylation and hydride reduction has been optimized using a rational, mechanistic-based approach. This approach enabled telescoping of the two steps

Global Trade Item Number

SKUGTIN
308919-100G4061837007941
308919-25G
308919-5G4061837007958

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