302473
Chlorobis(cyclooctene)rhodium(I),dimer
98%
Synonym(s):
[Rh(coe)2Cl]2
About This Item
Recommended Products
Quality Level
Assay
98%
form
powder
reaction suitability
core: rhodium
reagent type: catalyst
mp
190 °C (dec.) (lit.)
SMILES string
Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4
InChI
1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI key
GQPAPAIPOLEZHT-XFCUKONHSA-L
Application
- To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
- In direct C-arylation of N-unprotected indoles and pyrroles.
- In the carboxylation of arenes via C-H bond activation.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
302473-1G:4548173922089
302473-BULK:
302473-VAR:
302473-100MG:
302473-500MG:
302473-250MG:4548173922096
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Lewis and co-workers have recently disclosed a highly functional-group compatible Rh-catalyzed C-H bond activation for the rapid synthesis of functionalized heterocycles.
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