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302392

Sigma-Aldrich

Methyl 3-bromo-2-(bromomethyl)propionate

98%

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About This Item

Linear Formula:
(BrCH2)2CHCO2CH3
CAS Number:
22262-60-8
Molecular Weight:
259.92
MDL number:
MFCD00011534
UNSPSC Code:
12352100
PubChem Substance ID:
24858250
NACRES:
NA.22

Assay

98%

form

liquid

refractive index

n20/D 1.508 (lit.)

bp

60-62 °C/0.4 mmHg (lit.)

density

1.82 g/mL at 25 °C (lit.)

functional group

bromo
ester

SMILES string

COC(=O)C(CBr)CBr

InChI

1S/C5H8Br2O2/c1-9-5(8)4(2-6)3-7/h4H,2-3H2,1H3

InChI key

USXVPPOARMSYGY-UHFFFAOYSA-N

Related Categories

Application

Methyl 3-bromo-2-(bromomethyl)propionate was used in synthesis of sultams and (S)-1-benzyl-3-hydroxypyrrolidine.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

302392-VAR:
302392-BULK:
302392-5G:
302392-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
1408927
04808JJ
14324KH
11624AH
06701PD

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Alan Rolfe et al.
Organic & biomolecular chemistry, 8(9), 2198-2203 (2010-04-20)
The synthesis of small organic molecules as probes for discovering new therapeutic agents has been an important aspect of chemical-biology. Herein we report a reagent-based, diversity-oriented synthetic (DOS) strategy to probe chemical and biological space via a "Click, Click, Cyclize"

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